diff --git a/Include/cpython/unicodeobject.h b/Include/cpython/unicodeobject.h
index e75b5e154943dc..51eb998db4ab6a 100644
--- a/Include/cpython/unicodeobject.h
+++ b/Include/cpython/unicodeobject.h
@@ -446,17 +446,12 @@ PyAPI_FUNC(PyObject*) PyUnicode_FromKindAndData(
    Like PyUnicode_AsUTF8AndSize(), this also caches the UTF-8 representation
    in the unicodeobject.
 
-   _PyUnicode_AsString is a #define for PyUnicode_AsUTF8 to
-   support the previous internal function with the same behaviour.
-
    Use of this API is DEPRECATED since no size information can be
    extracted from the returned data.
 */
 
 PyAPI_FUNC(const char *) PyUnicode_AsUTF8(PyObject *unicode);
 
-#define _PyUnicode_AsString PyUnicode_AsUTF8
-
 /* === Characters Type APIs =============================================== */
 
 /* These should not be used directly. Use the Py_UNICODE_IS* and
diff --git a/Misc/NEWS.d/next/C API/2023-07-22-14-40-48.gh-issue-106320.H3u7x4.rst b/Misc/NEWS.d/next/C API/2023-07-22-14-40-48.gh-issue-106320.H3u7x4.rst
new file mode 100644
index 00000000000000..1e0ba0d71e7555
--- /dev/null
+++ b/Misc/NEWS.d/next/C API/2023-07-22-14-40-48.gh-issue-106320.H3u7x4.rst	
@@ -0,0 +1,5 @@
+Remove private ``_PyUnicode_AsString()`` alias to
+:c:func:`PyUnicode_AsUTF8`. It was kept for backward compatibility with
+Python 3.0 - 3.2. The :c:func:`PyUnicode_AsUTF8` is available since Python
+3.3. The :c:func:`PyUnicode_AsUTF8String` function can be used to keep
+compatibility with Python 3.2 and older. Patch by Victor Stinner.